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Crystal Chemistry and Properties of Materials with Quasi-One-Dimensional Structures: A Chemical and Physical Synthetic Approach (Physics and Chemistry of Materials with B #5)
by J. RouxelThere is no doubt that in the development of the Physics and Chemistry of Solids during the last fifteen years, the very important place taken by low-dimensional compounds will be remembered as a major event. Dealing very widely at the beginning with two-dimensional structures and intercalation chemistry, this theme progressively evolved as the synthesis of one-dimensional conductors increased, along with the observation of their remarkable properties. Beyond the classical separation of the traditional disciplines, essential progress has stemmed each time from the concerted efforts of, and overlapping between, chemists, experimental physicists, and theoreticians. This book is a synthetic approach which aims to retrace these united efforts. The observation and characterization of charge density waves in their static or dynamic aspects have been the main points to attract the interest of researchers. Two broad categories of compounds have been the material basis of these observa tions: transition-metal polychalcogenides and either condensed-cluster phases or bronze-type compounds. These families are referred to throughout the various chapters of this book, thus illustrating the continuous progress of concepts in this domain and, at the same time, providing the first synthetic and exhaustive view of this group of materials.
Crystal Chemistry of Condensed Phosphates
by A. DurifIn this reference, the author thoroughly reviews the current state of condensed phosphate chemistry. A unique feature of this volume is an examination of the recent developments in X-ray structural techniques, reporting on fundamental results obtained through their use. Enhanced by comprehensive tables reporting crystal data, chapters identify and characterize more than 2,000 compounds. Additional features include a concise survey of the historical development of condensed phosphate chemistry; the presently accepted classification system; a review of each family of condensed phosphates and much more.
Crystal Chemistry of High-Tc Superconducting Copper Oxides (Springer Series in Materials Science #15)
by Bernard Raveau Claude Michel Maryvonne Hervieu Daniel GroultThe recent discovery of high-temperature superconductivity in copper based oxides is an event of major importance not only with respect to the physical phenomenon itself but also because it definitely shows that solid state chemistry, and especially the crystal chemistry of oxides, has a crucial place in the synthesis and understanding of new materials for future appli cations. The numerous papers published in the field of high Tc supercon ductors in the last five years demonstrate that the great complexity of these materials necessitates a close collaboration between physicists and solid state chemists. This book is based to a large extent on our experience of the crystal chemistry of copper oxides, which we have been studying in the laboratory for more than twelve years, but it also summarizes the main results which have been obtained for these compounds in the last five years relating to their spectacular superconducting properties. We have focused on the struc ture, chemical bonding and nonstoichiometry of these materials, bearing in mind that redox reactions are the key to the optimization of their supercon ducting properties, owing to the importance of the mixed valence of copper and its Jahn-Teller effect. We have also drawn on studies of extended defects by high-resolution electron microscopy and on their creation by ir radiation effects.
Crystal Clear: The Autobiographies of Sir Lawrence and Lady Bragg
by A. M. Glazer and Patience ThomsonCrystal Clear takes you behind the scenes in the life of one of the most prominent scientists of the twentieth century, William Lawrence Bragg (WLB) - an innovative genius, who together with his father, William Henry Bragg (WHB) founded and developed a whole new branch of science, X-ray Crystallography. The main body of the text contains the hitherto unpublished autobiographies of both WLB and his wife, Alice. Alice Bragg was a public figure in her own right. She was Mayor of Cambridge and National Chairman of the Marriage Guidance Council among other roles. She and WLB were as different as chalk and cheese. Their autobiographies complement each other to give a rounded picture of the real personalities behind their public appearance. They write of their travels, their family life, their friends and their joys and sorrows. They write most of all about each other. Their younger daughter, Patience Thomson, provides anecdotes and vignettes, bringing her parents to life. She has also included extracts from previously unpublished letters and from articles which Alice Bragg wrote for National newspapers. The result is an unusual insight into the lives of two distinguished people. The two accounts reveal a fascinating interaction between these two characters, neither of whom could have achieved on this scale without the other. There is an underlying love story here which humanises and transforms. This is a unique book, adopting an original viewpoint, which will take the reader far beyond the scope of a normal biography.
Crystal Clear: The Autobiographies of Sir Lawrence and Lady Bragg
by A. M. Glazer Patience ThomsonCrystal Clear takes you behind the scenes in the life of one of the most prominent scientists of the twentieth century, William Lawrence Bragg (WLB) - an innovative genius, who together with his father, William Henry Bragg (WHB) founded and developed a whole new branch of science, X-ray Crystallography. The main body of the text contains the hitherto unpublished autobiographies of both WLB and his wife, Alice. Alice Bragg was a public figure in her own right. She was Mayor of Cambridge and National Chairman of the Marriage Guidance Council among other roles. She and WLB were as different as chalk and cheese. Their autobiographies complement each other to give a rounded picture of the real personalities behind their public appearance. They write of their travels, their family life, their friends and their joys and sorrows. They write most of all about each other. Their younger daughter, Patience Thomson, provides anecdotes and vignettes, bringing her parents to life. She has also included extracts from previously unpublished letters and from articles which Alice Bragg wrote for National newspapers. The result is an unusual insight into the lives of two distinguished people. The two accounts reveal a fascinating interaction between these two characters, neither of whom could have achieved on this scale without the other. There is an underlying love story here which humanises and transforms. This is a unique book, adopting an original viewpoint, which will take the reader far beyond the scope of a normal biography.
Crystal Cohesion and Conformational Energies (Topics in Current Physics #26)
by R. M. Metzger F. A. Momany B. D. Silverman D. E. WilliamsWith the advent of X-ray diffraction and crystal structure determination in 1912 researchers in physics and chemistry began investigating the problem of crystal co hesion, i. e. , on the question of what holds crystals together. The names of M. Born, E. Madelung, P. P. Ewald, F. Bloch, E. P. Wigner, and J. E. Mayer are, in particular, associated with the pre-1940 work on the cohesion of inorganic lattices. The advent of digital computers brought along great advances in the detailed understanding of ionic crystals, molecular crystals, and metals. The work of P. O. Lowdin and r A. I. Kitaigorodosky are seminal i these more recent advances. This volume is a collection of specialist reports on a subset of the general problem of crystal cohesion. It is intended for researchers and advanced students in solid-state chemistry and physics, and biochemistry. WILLIAMS reports on the mole cule-independent empirical parameters for dispersion and repulsion that explain, and can predict, the cohesive energy of neutral organic lattices. MOMANY applies similar procedures to the conformational energy problem and shows how they can be used for the pharmacological problems of polypeptide drug design. METZGER uses quantum-mechanical molecule-dependent atom-in-molecule charges, dipole moments, and polarizabilities to study the cohesion of organic ionic (semiconducting) and par tially ionic (metallic) lattices. SILVERMAN emphasizes, with quantum-mechanical dimer calculations, the importance of dispersive interactions for the observed stacking modes in organic metallic lattices.
Crystal Defects and Crystalline Interfaces
by Walter BollmannIt is nonnal for the preface to explain the motivation behind the writing of the book. Since many good books dealing with the general theory of crystal defects already exist, a new book has to be especially justified, and here its main justification lies in its treatment of crystal line interfaces. About 1961, the work of the author, essentially based on the fundamental work of Professor F. C. Frank, started to branch away from the main flow of thought in this field and eventually led to a general geometrical theory which is presented as a whole for the first time in this book. Although nearly all that is presented has already been published in different journals and symposia, it might be difficult for the reader to follow that literature, as a new terminology and new methods of analysis had to be developed. Special emphasis is given to discussion and many diagrams are included in order that a clear view of the basic concepts be obtained. Intennediate summaries try to bring out the main points of the chapters. Instead of specific exercises, general suggestions for them are given. The part up to chapter 9 is considered more or less as introductory, so that the book can be studied without specific knowledge of crystals and crystal defects. The presentation of that part developed out of lectures given by the author at the Swiss Federal Institute of Technology (ETH) in Zurich.
Crystal Engineering: From Molecules and Crystals to Materials (Nato Science Series C: #538)
by Dario Braga Fabrizia Grepioni A. Guy OrpenCrystal engineering is an interdisciplinary area that cuts across the traditional subdivisions of chemistry. Fuelled by our increasingly precise understanding of the chemistry and properties of supramolecular systems, interest in the potential of the field has increased rapidly. The topics discussed in the 28 contributions in this book provide a state-of-the-art description of the field and offer new research ideas that, if pursued, will serve to strengthen the field at the interface between supramolecular chemistry and materials science.
Crystal Fields for Transition-Metal Ions in Laser Host Materials
by Clyde A. MorrisonA researcher trying to predict or interpret spectra of transition metal ionsin possible laser host materials is confronted with a variety of different methods of describing the same physical situation. This book provides a systematic approach to the applied theory of crystal-field interactions of transition metal ions in 49 crystalline hosts that are or show promise of being good laser materials. The tables that make up the main part of the book present the experimentally determined parameters of the 3dN, 4dN, and 5dN transition-metal ions in the second, third, and fourth ionization states. These parameters have been converted to Slater and crystal-field parameters. The book is a source for research workers in laser development and in crystal-field theory, and for graduate students of solid state chemistry and physics.
Crystal Growth: Theory and Techniques Volume 1
by C. H. GoodmanIn the last decade or so the growth of single crystals has assumed enormous importance for both academic research, and technology (particu larly in the field of 'electronics'). The range of fields involved is great: from electro-optics to metal corrosion, from semiconductors to magnetic bubble materials-one can add to the list almost indefinitely. However, while the general principles of crystal growth can be applied aImost right across the board, it turns out that the precise way in which one can grow a particular crystal best varies considerably from material to material. This, of course, is to emphasise the obvious; nonetheless, except in specialised papers in the scientific litera ture , little attempt seems to have been made to deal in any detail with the causes of the difficulties in growing particular kinds of materials and with methods of circumventing them. These specialised papers may be inaccessible, and in any case cannot be, usually, very broad in scope or detailed in treatment simply because of the pressure to keep papers short. And unfortunately few specialised monographs seem to have been produced. These points and others similar emerged repeatedly in discussions with crystal growers from aU parts of the World and indicated that there was a need for a publication which would deal in detail with problems and techniques for specialised areas of crystal growth.
Crystal Growth: Theory and Techniques Volume 2
by C. H. GoodmanThe science and art of crystal growing continue to flourish; even with increasing understanding of the science, "feel" and skill continue to play their vital part, as was so clearly evidenced at the recent Boston International Conference on Crystal Growth. The aim of this volume, the same as that of the first, is to try to improve understanding by providing detailed discussions of crystal growth techniques and problems that arise with them. The published paper in the specialized literature is too limited a vehicle, by convention and by editorial pressure on length, to discuss matters in detail, yet it is in the small details born of experience that vital information can often lie concealed. A major aim of this series, therefore, has been to encourage contributors to describe rather fully what has been achieved in their special fields. The next volume of this series is now well underway and plans for Volume 4 are advanced. If you, the reader, feel that some important aspect of crystal growth is being unjustifiably neglected, perhaps you should consider offering a contribution! And even if you do not wish to do that, please do offer criticism-preferably constructive. I hope that the present volume will prove as useful and interesting to crystal growers as apparently did the first volume of the series; certainly the warm commendations that that volume has elicited were a great encouragement for the present work. Finally it is a pleasure to thank Standard Telecommunication Laboratories for its continuing support.
Crystal Growth: Principles and Progress (Updates in Applied Physics and Electrical Technology)
by A.W. VereThis book is the second in a series of scientific textbooks designed to cover advances in selected research fields from a basic and general viewpoint, so that only limited knowledge is required to understand the significance of recent developments. Further assistance for the non-specialist is provided by the summary of abstracts in Part 2, which includes many of the major papers published in the research field. Crystal Growth of Semiconductor Materials has been the subject of numerous books and reviews and the fundamental principles are now well-established. We are concerned chiefly with the deposition of atoms onto a suitable surface - crystal growth - and the generation of faults in the atomic structure during growth and subsequent cooling to room temperature - crystal defect structure. In this book I have attempted to show that whilst the fundamentals of these processes are relatively simple, the complexities of the interactions involved and the individuality of different materials systems and growth processes have ensured that experimentally verifiable predictions from scientific principles have met with only limited success - good crystal growth remains an art. However, recent advances, which include the reduction of growth temperatures, the reduction or elimination of reactant transport variables and the use of better-controlled energy sources to promote specific reactions, are leading to simplified growth systems.
Crystal Growth and Evaluation of Silicon for VLSI and ULSI
by Golla ErannaSilicon, as a single-crystal semiconductor, has sparked a revolution in the field of electronics and touched nearly every field of science and technology. Though available abundantly as silica and in various other forms in nature, silicon is difficult to separate from its chemical compounds because of its reactivity. As a solid, silicon is chemical
Crystal Growth Bibliography: Supplement (Solid State Physics Literature Guides #11)
Man's first experience with the ordered state of matter to which we now apply the generic term "crystals" came about when he found specimens of some of the natural crystalline mineral substances that are re latively common in the surface and near-surface areas of the earth's crust. His first widespread use of these natural materials in which their crystalline nature was of importance was undoubtedly in fabricating jewelry and otherwise adorning his weapons, tools, and household items. Both the Old and New Testa ments of the Bible document the use of crystalline gems, and the Romans are credited with first employing diamonds-a metastable crystalline form of carbon-in jewelry. Various civilizations appear to have ascribed magical powers to some natural crystals, and they are known to have been widely accepted in Europe as having medicinal properties during the Middle Ages. Given early man's appreciation of the symmetry and beauty of natural crystals, it is not surprising that his earliest interest in working with these materials appears to have been directed toward techniques for duplicating or manufacturing these sub stances that were so highly valued as gems. Although the exact beginning of the science that we now know as "crystal growth" cannot be precisely specified, we do know that Robert Boyle had attempted to grow crystals that could be used as gems prior to 1672. Much later, in 1873, M. A.
Crystal Growth from the Melt (Crystals #12)
by Georg Müller1 The content ofthis article is based on a German book version ) which appeared at the end of the year 1986. The author tried to incorporate - as far as possible - new important results published in the last year. But the literature in the field of "convection and inhomogeneities in crystal growth from the melt" has increased so much in the meantime that the reader and the collegues should make allowance for any incompleteness, also in the case that their important contributions have not been cited. This could for example hold for problems related to the Czochralski growth. But especially for this topic the reader may be refered to the forthcoming volume of this series, which contains special contributions on "Surface Tension Driven Flow in Crystal Growth Melts" by D. Schwabe and on "Convection in Czochralski Melts" by M. Mihelcic, W. Uelhoff, H. Wenzl and K. Wingerath. The preparation of this manuscript has been supported by several women whose help is gratefully acknowledged by the autor: Mrs. Gisela Neuner for the type writing, Mrs. Abigail Sanders, Mrs. Fiona Eels and especially Prof. Nancy Haegel for their help in questions of the English language and Mrs. Christa Weber for reading corrections. Also the good cooperation with the Springer Verlag, especially Mrs. Bohlen and with the managing editor of Crystals, Prof. H. C. Freyhardt, who critically read the manuscript, is acknowledged.
Crystal Growth in Science and Technology (Nato Science Series B: #210)
by H. Arend J. HulligerScience and art of crystal growth represent an interdisciplinary activity based on fundamental principles of physics, chemistry and crystallography. Crystal growth has contributed over the years essentially to a widening of knowledge in its basic disciplines and has penetrated practically into all fields of experimental natural sciences. It has acted, more over, in a steadily increasing manner as a link between science and technology as can be seen best, for example, from the achievements in modern microelectronics. The aim of the course "Crystal Growth in Science and Technology" being to stress the interdisciplinary character of the subject, selected fundamental principles are reviewed in the following contributions and cross links between basic and applied aspects are illustrated. It is a very well-known fact that the intensive development of crystal growth has led to a progressive narrowing of interests in highly specialized directions which is in particular harmful to young research scientists. The organizers of the course did sincerely hope that the program would help to broaden up the horizon of the participants. It was equally their wish to contribute within the traditional spirit of the school of crystallography in Erice to the promotion of mutual understanding, personal friendship and future collaboration between all those who were present at the school.
Crystal Growth of Silicon for Solar Cells (Advances in Materials Research #14)
by Kazuo Nakajima Noritaka UsamiThis book, a continuation of the series “Advances in Materials Research,” is intended to provide the general basis of the science and technology of crystal growth of silicon for solar cells. In the face of the destruction of the global environment,the degradationofworld-widenaturalresourcesandtheexha- tion of energy sources in the twenty-?rst century, we all have a sincere desire for a better/safer world in the future. In these days, we strongly believe that it is important for us to rapidly developanewenvironment-friendlycleanenergyconversionsystemusingsolar energyastheultimatenaturalenergysource. Forinstance,mostofournatural resources and energy sources will be exhausted within the next 100 years. Speci?cally, the consumption of oil, natural gas, and uranium is a serious problem. Solar energy is the only ultimate natural energy source. Although 30% of total solar energy is re?ected at the earth’s surface, 70% of total solar energy can be available for us to utilize. The available solar energy amounts to severalthousand times larger than the world’s energy consumption in 2000 of about 9,000 Mtoe (M ton oil equivalent). To manage 10% of the world’s energy consumption at 2050 by solar energy, we must manufacture 40 GW solar cells per year continuously for 40 years. The required silicon feedstock is about 400,000 ton per year. We believe that this is an attainable target, since it can be realized by increasing the world production of silicon feedstock by 12times asmuchasthe presentproductionat2005.
Crystal Growth Technology: From Fundamentals and Simulation to Large-scale Production
by Hans J. Scheel Peter CapperIn this book top experts treat general thermodynamic aspects of crystal fabrication; numerical simulation of industrial growth processes; commercial production of bulk silicon, compound semiconductors, scintillation and oxide crystals; X-ray characterization; and crystal machining. Also, the role of crystal technology for renewable energy and for saving energy is discussed. It will be useful for scientists and engineers involved in crystal and epilayer fabrication as well as for teachers and graduate students in material science, chemical and metallurgical engineering, and micro- and optoelectronics, including nanotechnology.
Crystal Growth Technology
by Hans J. Scheel Tsuguo FukudaThis volume deals with the technologies of crystal fabrication, of crystal machining, and of epilayer production and is the first book on industrial and scientific aspects of crystal and layer production. The major industrial crystals are treated: Si, GaAs, GaP, InP, CdTe, sapphire, oxide and halide scintillator crystals, crystals for optical, piezoelectric and microwave applications and more. Contains 29 contributions from leading crystal technologists covering the following topics: * General aspects of crystal growth technology * Silicon * Compound semiconductors * Oxides and halides * Crystal machining * Epitaxy and layer deposition Scientific and technological problems of production and machining of industrial crystals are discussed by top experts, most of them from the major growth industries and crystal growth centers. In addition, it will be useful for the users of crystals, for teachers and graduate students in materials sciences, in electronic and other functional materials, chemical and metallurgical engineering, micro-and optoelectronics including nanotechnology, mechanical engineering and precision-machining, microtechnology, and in solid-state sciences.
Crystal Identification with the Polarizing Microscope
by R.E. Stoiber S.A. MorseSome of the simpler measurements of optical mineralogy are so precise and powerful that they give satisfaction to beginning students. Not long after mastering the strike and dip of rock surfaces with the Brunton compass, many geology students are able to determine precisely the identity of quartz, or the anorthite content of plagioclase, or the magne sium ratio of pyroxene with the polarizing or petrographic microscope, by means of measuring refractive index to better than one part in a thousand. Very little training and almost no theory are needed to achieve these skills. But there inevitably comes a time when theory is needed, either to get on with the art, or simply to reconstruct from first principles what is going on, when rote memory fails. In this book we hope to provide both the rote methods and the theoretical background for practitioners at all levels of experience. We draw from several careers-ours, our colleagues', and our students' -in teaching the subject at various levels of sophistication. Our book is intended to serve the needs of industrial and forensic scientists as well as petrogra phers who deal with rocks. Much of our treatment is based on new research, both in matters of presentation and in the optical determination of minerals and other materials.
The Crystal Lattice: Phonons, Solitons, Dislocations, Superlattices
by Arnold M. KosevichThe aim of this successful book is to describe and analyse peculiarities of classical and quantum dynamics of a crystal as a spatially periodic structure. In the second revised and updated edition, the author focuses on low-dimensional models of crystals and on superlattices. Both traditional questions like the spectrum of vibrations, the idea of phonon gas, dislocations etc. and new aspects like the theory of quantum crystals, solitons in 1D crystals, dislocation theory of melting of 2D crystals etc. are discussed. The author gives an explanation of a set of phenomena which entered into solid state physics during the last decades. It is shown that the crystal properties are sensitive to the dimension of the crystal and its defect structure, and depend slightly on whether the periodic structure consists of atoms, or electrical dipoles, or magnetic moments (spins). Considerable attention is devoted to the dislocation mechanisms as a basis of the theory of plasticity and numerous technological applications of crystalline materials.
Crystal-Liquid-Gas Phase Transitions and Thermodynamic Similarity
by Vladimir P. Skripov Mars Z. FaizullinProfessor Skripov obtained worldwide recognition with his monograph "Metastable liquids", published in English by Wiley & Sons. Based upon this work and another monograph published only in Russia, this book investigates the behavior of melting line and the properties of the coexisting crystal and liquid phase of simple substances across a wide range of pressures, including metastable states of the coexisting phases. The authors derive new relations for the thermodynamic similarity for liquid-vapour phase transition, as well as describing solid-liquid, liquid-vapor and liquid-liquid phase transitions for binary systems employing the novel methodology of thermodynamic similarity.
Crystal Optics: Properties and Applications
by Ashim Kumar BainReviews the properties and applications of photo-elastic, acousto-optic, magneto-optic, electro-optic, and photorefractive materials This book deals with the basic physical properties and applications of photo-elastic, acousto-optic, magneto-optic, electro-optic, and photorefractive materials. It also provides up-to-date information on the design and applications of various optoelectronic devices based on these materials. The first chapter of Crystal Optics: Properties and Applications covers the basic concepts of crystal optics, such as index ellipsoid or optical indicatrix, crystal symmetry, wave surface, birefringence, and the polarization of light. Chapter 2 reviews the physical phenomena of crystal optics in isotropic and crystalline materials. It describes in detail research information on modern photoelastic materials and reviews the up-to-date photoelastic device applications. Chapter 3 develops the underlying theory of acousto-optics from first principles, formulating results suitable for subsequent calculations and design. The fourth chapter describes the basic principles of magneto-optic effects and mode of interaction with magnetic materials. The fifth chapter provides an understanding of the physical phenomenon of the linear and quadratic electro-optic effects in isotropic and crystalline materials. The last chapter collects many of the most important recent developments in photorefractive effects and materials, and pays special attention to recent scientific findings and advances on photorefractive materials and devices. -Features up to date information on the design and applications of various optoelectronic devices -Looks at the basic concepts of crystal optics, including the polarization of light, effects of reflection and transmission of polarization and light polarizing devices, and more -Pays special attention to design procedures for the entire range of acousto-optic devices and various applications of these devices -Provides research information on modern magneto-optic materials and reviews the up-to-date magneto-optic device applications?up to terahertz (THz) regime Crystal Optics: Properties and Applications is an excellent book for the scientific community working in the field, including researchers, lecturers, and advanced students.
Crystal Optics: Properties and Applications
by Ashim Kumar BainReviews the properties and applications of photo-elastic, acousto-optic, magneto-optic, electro-optic, and photorefractive materials This book deals with the basic physical properties and applications of photo-elastic, acousto-optic, magneto-optic, electro-optic, and photorefractive materials. It also provides up-to-date information on the design and applications of various optoelectronic devices based on these materials. The first chapter of Crystal Optics: Properties and Applications covers the basic concepts of crystal optics, such as index ellipsoid or optical indicatrix, crystal symmetry, wave surface, birefringence, and the polarization of light. Chapter 2 reviews the physical phenomena of crystal optics in isotropic and crystalline materials. It describes in detail research information on modern photoelastic materials and reviews the up-to-date photoelastic device applications. Chapter 3 develops the underlying theory of acousto-optics from first principles, formulating results suitable for subsequent calculations and design. The fourth chapter describes the basic principles of magneto-optic effects and mode of interaction with magnetic materials. The fifth chapter provides an understanding of the physical phenomenon of the linear and quadratic electro-optic effects in isotropic and crystalline materials. The last chapter collects many of the most important recent developments in photorefractive effects and materials, and pays special attention to recent scientific findings and advances on photorefractive materials and devices. -Features up to date information on the design and applications of various optoelectronic devices -Looks at the basic concepts of crystal optics, including the polarization of light, effects of reflection and transmission of polarization and light polarizing devices, and more -Pays special attention to design procedures for the entire range of acousto-optic devices and various applications of these devices -Provides research information on modern magneto-optic materials and reviews the up-to-date magneto-optic device applications?up to terahertz (THz) regime Crystal Optics: Properties and Applications is an excellent book for the scientific community working in the field, including researchers, lecturers, and advanced students.
Crystal Optics with Spatial Dispersion, and Excitons (Springer Series in Solid-State Sciences #42)
by Vladimir M. Agranovich V. GinzburgSpatial dispersion, namely, the dependence of the dielectric-constant tensor on the wave vector (i.e., on the wavelength) at a fixed frequency, is receiving increased attention in electrodynamics and condensed-matter optics, partic ularly in crystal optics. In contrast to frequency dispersion, namely, the frequency dependence of the dielectric constant, spatial dispersion is of interest in optics mainly when it leads to qualitatively new phenomena. One such phenomenon has been weH known for many years; it is the natural optical activity (gyrotropy). But there are other interesting effects due to spatial dispersion, namely, new normal waves near absorption lines, optical anisotropy of cubic crystals, and many others. Crystal optics that takes spatial dispersion into account includes classical crystal optics with frequency dispersion only, as a special case. In our opinion, this fact alone justifies efforts to develop crystal optics with spatial dispersion taken into account, although admittedly its influence is smaH in some cases and it is observable only under rather special conditions. Furthermore, spatial dispersion in crystal optics deserves attention from another point as well, namely, the investigation of excitons that can be excited by light. We contend that crystal optics with spatial dispersion and the theory of excitons are fields that overlap to a great extent, and that it is sometimes quite impossible to separate them. It is our aim to show the true interplay be tween these interrelations and to combine the macroscopic and microscopic approaches to crystal optics with spatial dispersion and exciton theory.