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Electrochemistry at the Nanoscale (Nanostructure Science and Technology)
by Patrik Schmuki Sannakaisa VirtanenFor centuries, electrochemistry has played a key role in technologically important areas such as electroplating or corrosion. In recent decades, electrochemical methods are receiving increasing attention in important strongly growing fields of science and technology such as nanosciences (nanoelectrochemistry) and life-sciences (organic and biological electrochemistry). Characterization, modification and understanding of various electrochemical interfaces or electrochemical processes at the nanoscale, has led to a huge increase of the scientific interest in electrochemical mechanisms as well as of application of electrochemical methods in novel technologies. This book presents exciting emerging scientific and technological aspects of the introduction of the nanodimension in electrochemical approaches are presented in 12 chapters/subchapters.
Electrochemistry Crash Course for Engineers
by Slobodan PetrovicThis book is a concise introductory guide to understanding the foundations of electrochemistry. By using simplified classroom-tested methods developed while teaching the subject to engineering students, the author explains in simple language an otherwise complex subject that can be difficult to master for most. It provides readers with an understanding of important electrochemical processes and practical industrial applications, such as electrolysis processes, metal electrowinning, corrosion and analytical applications, and galvanic cells such as batteries, fuel cells, and supercapacitors. This powerful tutorial is a great resource for students, engineers, technicians, and other busy professionals who need to quickly acquire a solid understanding of the science of electrochemistry.
Electrochemistry for Corrosion Fundamentals (SpringerBriefs in Molecular Science)
by Toshiaki Ohtsuka Atsushi Nishikata Masatoshi Sakairi Koji FushimiThis brief is concerned with the fundamentals of corrosion of metallic materials and electrochemistry for better understanding of corrosion phenomena. Corrosion is related to both the environment and material properties, induced by electrochemical reactions at the interface between metallic materials and the environment as in aqueous and gaseous phases. In order to understand corrosion phenomena, knowledge of electrochemistry is thus required, and to investigate the cause of corrosion damage, appropriate electrochemical experiments must be performed. Corrosion scientists should therefore possess knowledge of both electrochemistry and its related experimental techniques. In this book, corrosion phenomena are introduced from the electrochemical aspect. Electrochemical techniques for the study of corrosion are then described with other techniques that can be combined with electrochemistry. Because this brief is characterized as starting with the fundamentals of corrosion and electrochemistry, it is accessible to undergraduate students as well as to graduate students who are beginning corrosion research.
Electrochemistry for Cultural Heritage (Monographs in Electrochemistry)
by Antonio Doménech-Carbó María Teresa Doménech-CarbóThis monograph overviews the importance of electrochemistry in the field of cultural heritage, including archaeology, conservation and restoration topics. The application of electrochemical techniques in these domains have experienced a notable growth during the last ten years, in particular with regards to the elucidation of composition, manufacturing techniques and chronology of archaeological artefacts. This book describes the application of solid state electrochemistry techniques for the use of samples at the nanogram level from paintings, metallic, ceramic, glass, glazed, wooden, and other objects, and it also includes the description of new dating procedures for archaeological objects made of these materials. It is a valuable contribution to the field of cultural heritage and will be of great interest to archaeologists, conservators and restorers as well as to physicists and chemists working on the scientific examination of works of art.
Electrochemistry for Ecologists
by John BockrisThe present decade might be described as one in which man in the affluent countries is finally realizing that there is a bill to pay at the end of the feast-a feast at which he has eaten without inhibition, without knowing there was any need for inhibition. But now, with the situation fully clear, there is a strange non plussedness about man's reactions. More oil wells are sought, and clean-up packages are proposed for the same old cars. There is no real awareness yet that this is the end of an era, that quite new technologies have to be built up, and that the time remaining for this is a shatteringly short 15-30 years. However, there are sources of energy other than the fossil fuels. Oil and natural gas will run out (i.e., become too expensive) in any case during the next two or three decades. There seems little point in waiting until fuel is actually rationed and cars can only be used to move from home through smog to work before we change to these new and clean sources. The time to start the change is now, for there is much to be done.
Electrochemistry for the Environment
by Christos Comninellis Guohua ChenWastewater treatment technology is undergoing a profound transformation due to the fundamental changes in regulations governing the discharge and disposal of h- ardous pollutants. Established design procedures and criteria, which have served the industry well for decades, can no longer meet the ever-increasing demand. Toxicity reduction requirements dictate in the development of new technologies for the treatment of these toxic pollutants in a safe and cost-effective manner. Fo- most among these technologies are electrochemical processes. While electrochemical technologies have been known and utilized for the tre- ment of wastewater containing heavy metal cations, the application of these p- cesses is only just a beginning to be developed for the oxidation of recalcitrant organic pollutants. In fact, only recently the electrochemical oxidation process has been rec- nized as an advanced oxidation process (AOP). This is due to the development of boron-doped diamond (BDD) anodes on which the oxidation of organic pollutants is mediated via the formation of active hydroxyl radicals.
Electrochemistry in a Divided World: Innovations in Eastern Europe in the 20th Century
by Fritz ScholzIn this collection of interrelated essays, the authors review landmark developments in electrochemistry building on biographic material and personal insight. The book facilitates understanding of the innate pathways of developments in electrochemical science as a result of lucky circumstances fitting to objective conditions. Thus the book will help to understand the present state of electrochemistry and offer inspiration for solving today’s scientific challenges. The authors as experienced electrochemists from the U.S., Western and Eastern Europe also provide guidance for scientific careers by presenting biographical examples of famous electrochemists.
Electrochemistry in Industry: New Directions
by Uziel LandauThis volume represents the proceedings of the International Symposium on Electrochemistry in Industry - New Directions, held at Case Institute of Technology of Case Western Reserve University on October 20-22, 1980. This symposium was one of a number held at Case Institute during the 1980 calendar year as part of its centennial celebration. The following faculty members from Case Institute of Technol ogy constituted the organizing committee for the symposium: Uziel Landau, Chairman Associate Professor of Chemical Engineering Robert Hehemann Professor of Metallurgy C. C. Liu Professor of Chemical Engineering Ernest Yeager Director of CLES and Professor of Chemistry All lectures at this symposium were by invitation. The manu scripts as received for all but two of the lectures are herein published in the order of presentation. Discussion submitted by participants in written form appears at the end of each paper. Part of the panel discussion on Future Trends in Major Electro chemical Industries has also been included in this volume. CONTENTS INTRODUCTION . . • • • . • 1 The Case Institute of Technology Centenial Celebration Case Laboratories for Electrochemical Studies THEME AND OBJECTIVES OF THE CONFERENCE: Ernest Yeager 3 I. Overview of Electrochemical Industries; Catalysis in Electrochemistry The Outlook for the Electrochemical Industry 5 V. de Nora Dimensionally Stable Anodes • • . • . . . . . . • . • . . 19 H. B. Beer Oxygen Electrodes for Industrial Electrolysis and 29 Electrochemical Power Generation . • . • • • E. Yeager II.
Electrochemistry in Ionic Liquids: Volume 1: Fundamentals
by Angel A. J. TorrieroThis set of two books dedicated to presenting the latest novel and advanced research from around the world in this exciting area. These books highlight the important properties of electrochemistry in ionic liquids – as opposed to the more commonly used aqueous and organic environments – and the many applications. Readers will find 20 chapters gathered in two books: The first volume critically discusses electrode-electrolyte interfacial processes, reference electrodes, ultramicroelectrode voltammetry and scanning electrochemical microscopy, semi-integral and convolution voltammetry, and small-angle X-ray scattering coupled with voltammetry. The structure and properties of protic ionic liquids, deep-eutectic solvents, task-specific ionic liquids, polymeric ion gels, and lithium-ion solvation, useful for electrochemical application is also critically discussed The second volumes major topics covered in this book include electrodeposition and electroless deposition, voltammetry of adhered microparticles, electrochemistry of organic and organometallic compounds, electrocatalytic reactions, oxygen reduction reaction, ionic liquids in surface protection and lubrication, current industrial application of ionic liquids, and challenges, issues and recycling methods of ionic liquids in industrial developments.
Electrochemistry in Ionic Liquids: Volume 2: Applications
by Angel A. J. TorrieroThis is a set of two books dedicated to presenting the latest novel and advanced research from around the world in this exciting area. These books highlight the important properties of electrochemistry in ionic liquids – as opposed to the more commonly used aqueous and organic environments – and the many applications. Readers will find 20 chapters gathered in two books : Electrochemistry in Ionic Liquids – Volume 1, Fundamentals: This book critically discusses electrode-electrolyte interfacial processes, reference electrodes, ultramicroelectrode voltammetry and scanning electrochemical microscopy, semi-integral and convolution voltammetry, and small-angle X-ray scattering coupled with voltammetry. The structure and properties of protic ionic liquids, deep-eutectic solvents, task-specific ionic liquids, polymeric ion gels, and lithium-ion solvation, useful for electrochemical application is also critically discussed. Electrochemistry in Ionic Liquids – Volume 2, Applications: The major topics covered in this book include electrodeposition and electroless deposition, voltammetry of adhered microparticles, electrochemistry of organic and organometallic compounds, electrocatalytic reactions, oxygen reduction reaction, ionic liquids in surface protection and lubrication, current industrial application of ionic liquids, and challenges, issues and recycling methods of ionic liquids in industrial developments.
Electrochemistry in Nonaqueous Solutions
by Kosuke IzutsuAn excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmentally-friendly solvents, such as room-temperature ionic liquids.
Electrochemistry in Organic Synthesis
by Jiri Volke Frantisek LiskaThis book has been written as an introduction to the electro synthesis of organic compounds, in particular for organic chemists. Both authors assume that the knowledge of electro chemistry of these specialists is rather poor and is usually based only on the remnants of the teaching in the courses on physical and analytical chemistry during their university stud ies. Even with Czech chemists one cannot expect - as it was in the past - the experience obtained in the courses on polaro graphy. This is the reason why it was deemed necessary to write an introductory text to the electro synthesis of organics both as regards the theoretical and the methodological point of view, i. e. the fundamentals, the experimental setup, the application of various working and reference electrodes, the shape and con struction of electrolysis cells, the use of suitable pro tic and aprotic solvents, the experience obtained with various sup porting electrolytes, the separation and isolation of products, as well as the use of inert gases which prevent the interaction of intermediates and of final products with, for example, oxygen or traces of water. - The second part of the book contains a systematic description of preparative organic electrochemical processes, the interpretation of their mechanisms and several prescriptions for synthesizing characteristical groups of com pounds. As a whole the book is not written in an exhaustive way.
Electrochemistry in Research and Development
by R. Kalvoda Roger ParsonsThis volume contains the papers presented at the UNESCO Scientific Forum on Chemistry in the Service of Mankind - Electrochemistry in Research and Development, held in Paris, June 4-6, 1984. Electrochemistry is concerned with the way electricity produces chemical changes and in turn chemical changes result in the production of electricity. This interaction forms the basis for an enormous variety of processes ranging from heavy industry through batteries to biological phenomena. Although there are many established applications, modern research has led to a great expansion in the possibilities for using electrochemistry in exciting future developments. To encourage this progress, UNESCO has set up an Expert Committee on Electrochemistry and its Applications in the European and North American region, which has already held a number of meetings devoted to specific topics. To achieve a synthesis of the main directions of development and to demonstrate the importance of these for the needs of our modern society, the Expert Committee organized a Forum on Electrochemistry in Research and Development. The object of this was to assess the future trends in research and development and to establish a dialogue between experts in electrochemistry and their colleagues in the many other disciplines which can make use of electrochemistry. The Forum was also intended to present electrochemistry and its applications in a form accessible to non-specialists so that science policy-makers will be aware of the potentialities of this subject for the future needs of mankind.
Electrochemistry in Transition: From the 20th to the 21st Century
by Brian E. Conway Oliver J. Murphy S. SrinivasanThis book originated out of the papers presented at the special symposium, "Electrochemistry in Transition-From the 20th to the 21st Century," scheduled by the Division of Colloid and Surface Science during the American Chemical Society meeting in Toronto. The symposium was in honor of Professor J. O'M. Bockris, who received the ACS award on "The Chemistry of Contemporary Technological Problems" (sponsored by Mobay Corporation) during this meeting and who also reached his 65th birthday in the same year. The symposium was of a multidisciplinary nature and encompassed the fields of theoretical and experimental elec trochemistry, surface science, spectroscopy, and electrochemical technology. The symposium also had an international flavor in that the participants represented several countries Australia, Belgium, Canada, Chile, England, Japan, Korea, the Netherlands, Poland, Switzer land, Venezuela, Yugoslavia, and the United States. The symposium was graciously sponsored by the ACS (Petroleum Research Fund and Division of Colloid and Surface Science), Alcan International, Dow Chemical Company, EG&G, Electrolyzer Corporation, Exxon, General Electric Company, IBM, Institute of Gas Technology, International Association of Hydrogen Energy, Johnson Matthey, Inc. , Kerr-McGee Corporation, Medtronics, and Texas A&M University (Center for Electrochemical Systems and Hydrogen Research and the Hampton Robinson Fund). The "theme" of the papers presented at the symposium covered not only significant contributions made to electrochemistry in the twentieth century, but also "New Horizons in Electrochemistry" for the twenty-first century. Thus, the scientists who presented papers were invited to contribute chapters to this book, having the same titles as the symposium.
Electrochemistry of Carbon Electrodes (Advances in Electrochemical Sciences and Engineering)
by Richard C. Alkire Philip N. Bartlett Jacek LipkowskiThe book sets the standard on carbon materials for electrode design. For the first time, the leading experts in this field summarize the preparation techniques and specific characteristics together with established and potential applications of the different types of carbon-based electrodes. An introductory chapter on the properties of carbon together with chapters on the electrochemical characteristics and properties of the different modifications of carbon such as carbon nanotubes, graphene, carbon fiber, diamond or highly ordered pyrolytic graphite provide the reader with the basics on this fascinating and ubiquitous electrode material. Cutting-edge technologies such as carbon electrodes in efficient supercapacitors, Li-ion batteries and fuel cells, or electrodes prepared by screen-printing are discussed, giving a complete but concise overview about the topic. The clearly structured book helps newcomers to grasp easily the principles of carbon-based electrodes, while researchers in fundamental and applied electrochemistry will find new ideas for further research on related key technologies.
Electrochemistry of Carbon Electrodes (Advances in Electrochemical Sciences and Engineering #34)
by P. N. Bartlett Richard C. Alkire Jacek LipkowskiThe book sets the standard on carbon materials for electrode design. For the first time, the leading experts in this field summarize the preparation techniques and specific characteristics together with established and potential applications of the different types of carbon-based electrodes. An introductory chapter on the properties of carbon together with chapters on the electrochemical characteristics and properties of the different modifications of carbon such as carbon nanotubes, graphene, carbon fiber, diamond or highly ordered pyrolytic graphite provide the reader with the basics on this fascinating and ubiquitous electrode material. Cutting-edge technologies such as carbon electrodes in efficient supercapacitors, Li-ion batteries and fuel cells, or electrodes prepared by screen-printing are discussed, giving a complete but concise overview about the topic. The clearly structured book helps newcomers to grasp easily the principles of carbon-based electrodes, while researchers in fundamental and applied electrochemistry will find new ideas for further research on related key technologies.
Electrochemistry of Cleaner Environments
by John BockrisOf the societal ills which are recognized as present in the Western countries during the 1970's, pollution of air and water is among the first. Whether the breathing of noxious gases acts biochemically as a source of mental irritation is not yet known. But it is not in doubt that reduction of the grime, smog, fouled water, and acrid air would lead to an increase in a feeling of well-being. Nor is it speculative to state that a reversal of the present trend to poison the atmosphere and the water is essential if man is to survive in a technological society. It was partly the lack of realization of the intrinsic nature of over potential in electrochemical reactions, * and hence the failure of the early fuel cells to come up to expectations, which led engineers at the turn of the century to rely upon the combustion of oil and coal for the production of energy, with the associated era of increasing atmospheric pollution.
Electrochemistry of Flotation of Sulphide Minerals
by Yuehua Hu Wei Sun Dianzuo Wang"Electrochemistry of Flotation of Sulphide Minerals" systematically covers various electrochemical measurements, especially electrochemical corrosive methods, electrochemical equilibrium calculations, surface analysis, semiconductor energy band theory as well as molecular orbital theory. Behaviour and mechanism of collectorless and collector-induced flotation of sulphide minerals in various flotation systems are also discussed. The example of electrochemical flotation separation of sulphide ores shows an industrial application. Prof. Yuehua Hu is a professor at the School of Minerals Processing & Bioengineering of Central South University and Vice Chairman of the Mineral Processing Committee of the China Nonferrous Metals Society. Dr. Wei Sun is an associate professor at the School of Minerals Processing & Bioengineering of Central South University. Prof. Dianzuo Wang is both a member of Chinese Academy of Sciences and Chinese Academy of Engineering, and a foreign associate of the National Academy of Engineering (USA).
Electrochemistry of Functional Supramolecular Systems (The Wiley Series on Electrocatalysis and Electrochemistry #6)
by Alberto Credi Paola Ceroni Margherita VenturiWith contributions from the most prominent experts around the world, this resource provides an accessible summary of electrochemical techniques and the applications of electrochemical concepts to molecular-level systems. It describes the most important electro-active functional supramolecular systems developed so far, including rotaxanes and catenanes as molecular machines and as elements for information processing; dendrimers as molecular batteries, sensors, light harvesting antennae, and drug delivery systems; and bio-hybrid devices.
Electrochemistry of Glasses and Glass Melts, Including Glass Electrodes (Schott Series on Glass and Glass Ceramics)
by Hans Bach Friedrich K. G. Baucke Dieter KrauseThis volume presents background information on the electrochemical behaviour of glass melts and solid glasses. The text lays the foundations for a sound understanding of physicochemical redox and ion transfer processes in solid or liquid glasses and the interpretation of experimental results. Other topics discussed include: control of production processes, the field-driven ion exchange between solutions and glasses or within electrochromic thin-film systems, mechanisms responsible for glass corrosion, the concept of optical basicity, and others. Throughout, the text contains practical examples enabling readers to study the various aspects of electrochemical processes in ion-conducting materials.
Electrochemistry of Immobilized Particles and Droplets
by Fritz Scholz Uwe Schröder Rubin GulaboskiImmobilizing particles or droplets on electrodes is a novel and most powerful technique for studying the electrochemical reactions of three-phase systems. It gives access to a wealth of information, ranging from quantitative and phase analysis to thermodynamic and kinetic data of electrode processes. Three-phase electrodes with immobilized droplets provide information on the electrochemistry of redox liquids and of compounds dissolved in inert organic liquids. Such measurements allow the determination of the Gibbs energies of the transfer of cations and anions between immiscible solvents, and thus make it possible to assess the hydrophobicity of ions – a property that is of great importance for pharmaceutical applications, biological studies, and for many fields of chemistry.The monograph gives, for the first time, a comprehensive overview of the results published in more than 300 papers over the last 15 years. The experiments are explained in detail, applications from many different fields are presented, and the theoretical basis of the systems is outlined.
Electrochemistry of Immobilized Particles and Droplets: Experiments with Three-Phase Electrodes
by Fritz Scholz Uwe Schröder Rubin Gulaboski Antonio Doménech-CarbóThis second edition of a successful and highly-accessed monograph has been extended by more than 100 pages. It includes an enlarged coverage of applications for materials characterization and analysis. Also a more detailed description of strategies for determining free energies of ion transfer between miscible liquids is provided. This is now possible with a “third-phase strategy” which the authors explain from theoretical and practical points of view. The book is still the only one detailing strategies for solid state electroanalysis. It also features the specific potential of the techniques to use immobilized particles (for studies of solid materials) and of immobilized droplets of immiscible liquids for the purpose of studying the three-phase electrochemistry of these liquids. This also includes studies of ion transfer between aqueous and immiscible non-aqueous liquids. The bibliography of all published papers in this field of research has been expanded from 318 to now 444 references in this second edition. Not only are pertinent references provided at the end of each chapter, but the complete list of the cited literature is also offered as a separate chapter for easy reference.
Electrochemistry of Insertion Materials for Hydrogen and Lithium (Monographs in Electrochemistry)
by Su-Il Pyun Heon-Cheol Shin Jong-Won Lee Joo-Young GoThe understanding of hydrogen/lithium insertion phenomena is of great importance for the development of the next generation of functional electrochemical devices such as rechargeable batteries, electrochromic devices, and fuel cells. This volume introduces a variety of viable electrochemical methods to identify reaction mechanisms and evaluate relevant kinetic properties of insertion electrodes. The authors also outline various ways to analyze anomalous behaviour of hydrogen/lithium transport through insertion electrodes.
Electrochemistry of Metal Chalcogenides (Monographs in Electrochemistry)
by Mirtat BouroushianThe author provides a unified account of the electrochemical material science of metal chalcogenide (MCh) compounds and alloys with regard to their synthesis, processing and applications. Starting with the chemical fundamentals of the chalcogens and their major compounds, the initial part of the book includes a systematic description of the MCh solids on the basis of the Periodic Table in terms of their structures and key properties. This is followed by a general discussion on the electrochemistry of chalcogen species, and the principles underlying the electrochemical formation of inorganic compounds/alloys. The core of the book offers an insight into available experimental results and inferences regarding the electrochemical preparation and microstructural control of conventional and novel MCh structures. It also aims to survey their photoelectrochemistry, both from a material-oriented point of view and as connected to specific processes such as photocatalysis and solar energy conversion. Finally, the book illustrates the relevance of MCh materials to various applications of electrochemical interest such as (electro)catalysis in fuel cells, energy storage with intercalation electrodes, and ion sensing.
Electrochemistry of Metal Complexes: Applications from Electroplating to Oxide Layer Formation
by Arvydas SurvilaA systematic analysis of electrochemical processes involving metal complexes. Starting with general considerations on equilibria in solutions and at interfaces as well as on mass transport, the text acquaints readers with the theory and common experimental practice for studying electrochemical reactions of metals complexes. The core part of the book deals with all important aspects of electroplating, including a systematic discussion of co-deposition of metals and formation of alloys. It also discusses such related subjects as oxide layer formation and hydrogen evolution as a side reaction.