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Electron Spin Resonance (ESR) Applications in Organic and Bioorganic Materials: Proceedings of the First European Meeting January 1990, Lyon, France

by B. Catoire

E.S.R. techniques which are mature from a fundamental point of view. now constitute a routine investigation tool in chemistry as well as in biophysics in order to study and to follow the behaviour of radical species. Among the practical applications. let us mention for instance : -diffusion phenomena (solid -solid. liquid -solid such as the diffusion of molecules through membranes. films fibers ... ). -study of radical species to improve the elaboration of materials with high added value (composites). -detection of ionised food. -liquid crystals. polymers. -radiochemistry. -targetting of drugs. toxicology. A better understanding of basic phenomena allows to optimize industrial products and processes applied as well as in advanced fields as in well established ones. The high sensivity of ESR Spectroscopy and its derived specific techniques (spin labelling. spin probe. spin trapping ... ) offer information on the fme morphological structure of the matter as well as on its behaviour under various treatments otherwise not available. A Symposium was organized in Lyon (France) in January 1990 to promote the use of ESR. Its originality was to deal with the practical applications of ESR to organic and bioorganic materials. The scope of this meeting was to enlarge the field of application from basic research to more applied subjects and this may concern industrial as well as academic researchers. Moreover. the purpose of this symposium was to promote exchanges between European specialists working in public or private areas.

Electron Spin Resonance in Semiconductors (Monographs on Electron Spin Resonance)

by Gordon Lancaster

Since the study of the solid state began it has been necessary to use increasingly refined experimental techniques, of which electron spin resonance is an important example, in the effort to gain information concerning the structure and properties of an immense and varied range of solids. In the last two decades the great commercial demand for solid-state electronic devices has stimulated research into the funda­ mental properties of semiconductors. At the same time as semiconductor devices were becoming techno­ logically important, the technique of electron spin resonance was first being used on a large scale, principally at the Clarendon Laboratory, Oxford. Both solid-state physics and electron spin resonance have now reached the stage where they are useful to each other, primarily in the realm of the atomic properties of matter. Dr Lancaster's book is one of a series of monographs that aims at covering as comprehensively as possible the field of electron spin resonance. His book has been written for those who wish to know some­ thing about the way in which the electron spin resonance technique has been used in the study of semiconductors. It also has value for specialists who may need an authoritative work of reference, and for workers in allied subjects who wish to use this technique to further their work. Much of his treatise deals with electron spin resonance in crystals of silicon and germanium containing specific impurities, as these materials are of greatest interest. Practical results are discussed wherever possible.

Electron Spin Resonance of Metal Complexes: Proceedings of the Symposium on ESR of Metal Chelates at the Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, held in Cleveland, Ohio, March 4–8, 1968

by Teh Yen

For a number of years, there existed a real gap between the science of metal complexes and that of electron spin resonance (ESR). Simple reasons account for this fact. At a certain stage of development the scientists engaged in investigations of metal complexes did not have access to ESR instrumen­ tation, while on the other hand, ESR theoreticians rarely had an interest in exploring the chemical applications of metal complexes. More recently chemical physicists have started to make intensive efforts to bridge the gap by applying the ESR technique to a wide range of chemical problems, particularly those involving transition metals and their complexes. In large measure the successes of the theory of the electronic structure of transition metal ions are due to the comprehensive and precise results of ESR studies by chemical physicists. On the other hand, chemists also seem to have realized lately that an immense amount of information can be obtained from ESR data. It is obvious, therefore, that a symposium bringing together the various disciplines was necessary, and there was little doubt that in such a symposium a considerable advantage could be gained from the exchange of information among scientists with different research interests. Consequently, a sym­ posium on "ESR of Metal Chelates" was held on March 4, 1968, at the Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, at the Cleveland Convention Center.

Electron Spin Resonance Spectroscopy in Medicine

by Ashutosh Kumar Shukla

This book examines various applications of electron spin resonance spectroscopy (ESR) in medicine, covering topics such as interactions between blood and nanoparticles, physical intricacy of HbNO complexes, parasitic diseases, oxidative stress measurement, polymerization of resinous materials used in dentistry, tooth dosimetry and dermatological applications. Instead of providing mathematical details, it focuses on the applications and data interpretation of ESR as an emerging tool. This book is intended for students and researchers interested in the field of ESR applications in translational research and medicine.

Electron Spin Resonance Spectroscopy of Organic Radicals

by Fabian Gerson Walter Huber

Electron spin resonance spectroscopy is the method used to determine the structure and life expectancy of a number of radicals. Written by Fabian Gerson and Walter Huber, top experts in the field of electron spin resonance spectroscopy, this book offers a compact yet readily comprehensible introduction to the modern world of ESR. Thanks to its comprehensive coverage, ranging from fundamental theory right up to the treatment of all important classes of organic radicals and triplet-state molecules that can be analyzed using ESR spectroscopy, this unique book is suitable for users in both research and industry. Instead of using complex mathematical derivations, the authors present a readily understandable approach to the field by interpreting sample spectra and classifying experimental data. In short, the ideal book for newcomers to the subject and an absolute must-have for everyone confronted with ESR spectroscopy and wanting to become acquainted with this widely-used method of analysis.

Electron Tomography: Three-Dimensional Imaging with the Transmission Electron Microscope

by Joachim Frank

This unique resource details the theory, working methods, and applications of electron tomographic techniques for imaging asymmetric, noncrystalline biological specimens.

Electron Tomography: Methods for Three-Dimensional Visualization of Structures in the Cell

by Joachim Frank

This definitive work provides a comprehensive treatment of the mathematical background and working methods of three-dimensional reconstruction from tilt series. Special emphasis is placed on the problems presented by limitations of data collection in the transmission electron microscope. The book, extensively revised and updated, takes the reader from biological specimen preparation to three-dimensional images of the cell and its components.

Electron Transfer: Mechanisms and Applications

by Shunichi Fukuzumi

Written by one of the top scientists in this field, this is a systematic overview of the fundamental concepts and powerful applications. The author presents the central theories and mechanisms in electron transfer, followed by several systems in nature where this is important, while also covering modern green applications. An invaluable resource for graduate students and researchers working in this field in academia and industry.

Electron Transfer: Mechanisms and Applications

by Shunichi Fukuzumi

Written by one of the top scientists in this field, this is a systematic overview of the fundamental concepts and powerful applications. The author presents the central theories and mechanisms in electron transfer, followed by several systems in nature where this is important, while also covering modern green applications. An invaluable resource for graduate students and researchers working in this field in academia and industry.

Electron Transfer: From Isolated Molecules to Biomolecules, Part 2 (Advances in Chemical Physics #232)

by Ilya Prigogine Stuart A. Rice

an integrated approach to electron transfer phenomena This two-part stand-alone volume in the prestigious Advances in Chemical Physics series provides the most comprehensive overview of electron transfer science today. It draws on cutting-edge research from diverse areas of chemistry, physics, and biology-covering the most recent developments in the field, and pointing to important future trends. This second volume offers the following sections: * Solvent control, including ultrafast solvation dynamics and related topics * Ultrafast electron transfer and coherence effects * Molecular electronics * Electron transfer and exciplex chemistry * Biomolecules-from electron transfer tubes to kinetics in a DNA environment Part One addresses the historical perspective, electron transfer phenomena in isolated molecules and clusters, general theory, and electron transfer kinetics in bridged compounds. Electron transfer science has seen tremendous progress in recent years. Technological innovations, most notably the advent of femtosecond lasers, now permit the real-time investigation of intramolecular and intermolecular electron transfer processes on a time scale of nuclear motion. New scientific information abounds, illuminating the processes of energy acquisition, storage, and disposal in large molecules, clusters, condensed phase, and biophysical systems. Electron Transfer: From Isolated Molecules to Biomolecules is the first book devoted to the exciting work being done in nonradiative electron transfer dynamics today. This two-part edited volume emphasizes the interdisciplinary nature of the field, bringing together the contributions of pioneers in chemistry, physics, and biology. Both theoretical and experimental topics are featured. The authors describe modern approaches to the exploration of different systems, including supersonic beam techniques, femtosecond laser spectroscopy, chemical syntheses, and methods in genetic and chemical engineering. They examine applications in such areas as supersonic jets, solvents, electrodes, semi- conductors, respiratory and enzymatic protein systems, photosynthesis, and more. They also relate electron transfer and radiationless transitions theory to pertinent physical phenomena, and provide a conceptual framework for the different processes. Complete with over two hundred illustrations, Part Two opens with solvent control issues, including electron transfer reactions and ultrafast solvation dynamics. Other topics include ultrafast electron transfer and coherence effects, molecular electronics, and electron transfer in exciplex chemistry. This volume concludes with a section on biomolecules-from electron transfer tubes to experimental electron transfer and transport in DNA. Timely, comprehensive, and authoritative, Electron Transfer: From Isolated Molecules to Biomolecules is an essential resource for physical chemists, molecular physicists, and researchers working in nonradiative dynamics today.

Electron Transfer: From Isolated Molecules to Biomolecules, Part 1 (Advances in Chemical Physics #230)

by Ilya Prigogine Stuart A. Rice

an integrated approach to electron transfer phenomena This two-part stand-alone volume in the prestigious Advances in Chemical Physics series provides the most comprehensive overview of electron transfer science today. It draws on cutting-edge research from diverse areas of chemistry, physics, and biology-covering the most recent developments in the field, and pointing to important future trends. This initial volume includes: * A historical perspective spanning five decades * A review of concepts, problems, and ideas in current research * Electron transfer in isolated molecules and in clusters * General theory, including useful algorithms * Spectra and electron transfer kinetics in bridged compounds The second volume covers solvent control, ultrafast electron transfer and coherence effects, molecular electronics, electron transfer and chemistry, and biomolecules. Electron transfer science has seen tremendous progress in recent years. Technological innovations, most notably the advent of femtosecond lasers, now permit the real-time investigation of intramolecular and intermolecular electron transfer processes on a time scale of nuclear motion. New scientific information abounds, illuminating the processes of energy acquisition, storage, and disposal in large molecules, clusters, condensed phase, and biophysical systems. Electron Transfer: From Isolated Molecules to Biomolecules is the first book devoted to the exciting work being done in nonradiative electron transfer dynamics today. This two-part edited volume emphasizes the interdisciplinary nature of the field, bringing together the contributions of pioneers in chemistry, physics, and biology. Both theoretical and experimental topics are featured. The authors describe modern approaches to the exploration of different systems, including supersonic beam techniques, femtosecond laser spectroscopy, chemical syntheses, and methods in genetic and chemical engineering. They examine applications in such areas as supersonic jets, solvents, electrodes, semi- conductors, respiratory and enzymatic protein systems, photosynthesis, and more. They also relate electron transfer and radiationless transitions theory to pertinent physical phenomena, and provide a conceptual framework for the different processes. Complete with over two hundred illustrations, Part One reviews developments in the field since its inception fifty years ago, and discusses electron transfer phenomena in both isolated molecules and in clusters. It outlines the general theory, exploring areas of the control of kinetics, structure-function relationships, fluctuations, coherence, and coupling to solvents with complex spectral density in different types of electron transfer processes. Timely, comprehensive, and authoritative, Electron Transfer: From Isolated Molecules to Biomolecules is an essential resource for physical chemists, molecular physicists, and researchers working in nonradiative dynamics today.

Electron Transfer Reactions in Organic Chemistry (Reactivity and Structure: Concepts in Organic Chemistry #25)

by Lennart Eberson

The subject of the book is electron transfer reactions in organic chemistry, with the emphasis on mechanistic aspects. The theoretical framework is that of the Marcus theory, well-known from its extensive use in inorganic chemistry. The book deals with definitions of electron transfer, theory of electron transfer reactions (Marcus' and Pross-Shaik's approach) experimental diagnosis of electron transfer reactions, examples from inorganic/organic reactants and purely organic reactants, electro- and photochemical electron transfer, electron transfer catalyzed reactions, connections between electron transfer and polar mechanisms, and applications of electron transfer, such as electrosynthesis of organic chemicals, photochemical energy storage, conducting organic materials and chemiluminescence. The approach is new in so far as no comparable book has been published. The book will be of value to anyone interested in keeping track of developments in physical organic chemistry.

Electron Transport in Compound Semiconductors (Springer Series in Solid-State Sciences #11)

by B.R. Nag

Discovery of new transport phenomena and invention of electron devices through exploitation of these phenomena have caused a great deal of interest in the properties of compound semiconductors in recent years. Extensive re­ search has been devoted to the accumulation of experimental results, par­ ticularly about the artificially synthesised compounds. Significant ad­ vances have also been made in the improvement of the related theory so that the values of the various transport coefficients may be calculated with suf­ ficient accuracy by taking into account all the complexities of energy band structure and electron scattering mechanisms. Knowledge about these deve­ lopments may, however, be gathered only from original research contributions, scattered in scientific journals and conference proceedings. Review articles have been published from time to time, but they deal with one particular material or a particular phenomenon and are written at an advanced level. Available text books on semiconductor physics, do not cover the subject in any detail since many of them were written decades ago. There is, there­ fore, a definite need for a book, giving a comprehensive account of electron transport in compound semiconductors and covering the introductory material as well as the current work. The present book is an attempt to fill this gap in the literature. The first chapter briefly reviews the history of the developement of compound semiconductors and their applications. It is also an introduction to the contents of the book.

Electron Transport in Nanosystems (NATO Science for Peace and Security Series B: Physics and Biophysics)

by Janez Bonca Sergei Kruchinin

Proceedings of the NATO Advanced Research Workshop on Electron Transport in Nanosystems Yalta, Ukraine 17-21 September 2007

Electron Transport in Quantum Dots

by Jonathan P. Bird

When I was contacted by Kluwer Academic Publishers in the Fall of 200 I, inviting me to edit a volume of papers on the issue of electron transport in quantum dots, I was excited by what I saw as an ideal opportunity to provide an overview of a field of research that has made significant contributions in recent years, both to our understanding of fundamental physics, and to the development of novel nanoelectronic technologies. The need for such a volume seemed to be made more pressing by the fact that few comprehensive reviews of this topic have appeared in the literature, in spite of the vast activity in this area over the course of the last decade or so. With this motivation, I set out to try to compile a volume that would fairly reflect the wide range of opinions that has emerged in the study of electron transport in quantum dots. Indeed, there has been no effort on my part to ensure any consistency between the different chapters, since I would prefer that this volume instead serve as a useful forum for the debate of critical issues in this still developing field. In this matter, I have been assisted greatly by the excellent series of articles provided by the different authors, who are widely recognized as some of the leaders in this vital area of research.

Electron Waves in Solids: Exploring the Foundations of Modern Technology (Springer Series in Solid-State Sciences #203)

by Navin Khaneja

This book explores the intricate world of electron behavior within solids, revealing them to be waves—a fundamental insight crucial to grasping modern electronics, computing, and solid-state devices. This comprehensive examination elucidates the factors determining material conductivity, distinguishing between conductors, insulators, and semiconductors. Through detailed analysis, the text illuminates the thermal agitation of solids, manifesting as vibrations known as phonons, which impede electron flow and contribute to electrical resistance. Readers gain insight into the production of electronic devices through semiconductor doping, exploring various device types and their functionalities. The book further investigates the temperature-dependent behavior of metal resistance, including the phenomenon of superconductivity, wherein resistance vanishes entirely at low temperatures—a phenomenon comprehensively elucidated within these pages. Moreover, the text unravels the mysteries of magnetism in solids, exploring how certain metals, such as iron, exhibit permanent magnetism. By probing into the underlying causes of magnetism, readers gain a deeper understanding of solid-state physics. Additionally, the book explores imaging techniques such as X-rays, offering insights into how scientists peer inside solids to decipher their internal structures and properties. Geared toward scientists and engineers, the book serves as an indispensable resource for mastering the foundational concepts of solid-state physics—a discipline indispensable to modern technology.

Electronic and Magnetic Excitations in Correlated and Topological Materials (Springer Theses)

by John S. Van Dyke

This ​thesis reports a major breakthrough in discovering the superconducting mechanism in CeCoIn5, the “hydrogen atom” among heavy fermion compounds. By developing a novel theoretical formalism, the study described herein succeeded in extracting the crucial missing element of superconducting pairing interaction from scanning tunneling spectroscopy experiments. This breakthrough provides a theoretical explanation for a series of puzzling experimental observations, demonstrating that strong magnetic interactions provide the quantum glue for unconventional superconductivity. Additional insight into the complex properties of strongly correlated and topological materials was provided by investigating their non-equilibrium charge and spin transport properties. The findings demonstrate that the interplay of magnetism and disorder with strong correlations or topology leads to complex and novel behavior that can be exploited to create the next generation of spin electronics and quantum computing devices.

Electronic and Magnetic Properties of Chiral Molecules and Supramolecular Architectures (Topics in Current Chemistry #298)

by Ron Naaman, David N H. Beratan and David N. Waldeck

Time-dependent density functional response theory for electronic chiroptical properties of chiral molecules; by Jochen Autschbach, Lucia Nitsch–Velasquez, and Mark Rudolph*Chiroptical Properties of Charge-Transfer Compounds; by Yoshihisa Inoue, Tadashi Mori*G-C content independent long-range charge transfer through DNA; by Tetsuro Majima*Induced chirality in porphiryn aggregates: the role of weak and strong interactions; by Roberto Purrello *Vibrational circular dichroism spectroscopy of chiral molecules in solution; by Yunjie Xu *Magneto-electric properties of self-assembled monolayers of chiral molecules; by Zeev Vager and Ron Naaman*Theory of adsorption induced chirality and electron transfer through chiral systems; by Spiros Skourtis and David Beratan *Chiral-selective surface chemistry induced by spin-polarized secondary electrons; by Richard Rosenberg

Electronic and Optical Properties of Conjugated Polymers (International Series of Monographs on Physics #159)

by William Barford

Conjugated polymers have important technological applications, including solar cells and light emitting devices. They are also active components in many important biological processes. In recent years there have been significant advances in our understanding of these systems, owing to both improved experimental measurements and the development of advanced computational techniques. The aim of this book is to describe and explain the electronic and optical properties of conjugated polymers. It focuses on the three key roles of electron-electron interactions, electron-nuclear coupling, and disorder in determining the character of the electronic states, and it relates these properties to experimental observations in real systems. A number of important optical and electronic processes in conjugated polymers are also described. The second edition has a more extended discussion of excitons in conjugated polymers. There is also a new chapter on the static and dynamical localization of excitons.

Electronic and Optical Properties of Conjugated Polymers (International Series of Monographs on Physics #159)

by William Barford

Conjugated polymers have important technological applications, including solar cells and light emitting devices. They are also active components in many important biological processes. In recent years there have been significant advances in our understanding of these systems, owing to both improved experimental measurements and the development of advanced computational techniques. The aim of this book is to describe and explain the electronic and optical properties of conjugated polymers. It focuses on the three key roles of electron-electron interactions, electron-nuclear coupling, and disorder in determining the character of the electronic states, and it relates these properties to experimental observations in real systems. A number of important optical and electronic processes in conjugated polymers are also described. The second edition has a more extended discussion of excitons in conjugated polymers. There is also a new chapter on the static and dynamical localization of excitons.

Electronic and Optical Properties of Graphite-Related Systems

by Chiun-Yan Lin Rong-Bin Chen Yen-Hung Ho Ming-Fa Lin

This book provides an overview of electronic and optical properties of graphite-related systems. It presents a well-developed and up-to-date theoretical model and addresses important advances in essential properties and diverse quantization phenomena. Key features include various Hamiltonian models, dimension-enriched carbon-related systems, complete and unusual results, detailed comparisons with the experimental measurements, clear physical pictures, and further generalizations to other emergent 2D materials. It also covers potential applications, such as touch-screen panel devices, FETs, supercapacitors, sensors, LEDs, solar cells, photodetectors, and photomodulators.

Electronic and Optical Properties of Graphite-Related Systems

by Chiun-Yan Lin Rong-Bin Chen Yen-Hung Ho Ming-Fa Lin

This book provides an overview of electronic and optical properties of graphite-related systems. It presents a well-developed and up-to-date theoretical model and addresses important advances in essential properties and diverse quantization phenomena. Key features include various Hamiltonian models, dimension-enriched carbon-related systems, complete and unusual results, detailed comparisons with the experimental measurements, clear physical pictures, and further generalizations to other emergent 2D materials. It also covers potential applications, such as touch-screen panel devices, FETs, supercapacitors, sensors, LEDs, solar cells, photodetectors, and photomodulators.

Electronic and Structural Properties of LaNiO₃-Based Heterostructures (Springer Theses)

by Jennifer Fowlie

This thesis explores an amazing family of oxide compounds - the nickelates - known for their metal-to-insulator transition and, in the case of LaNiO3, to be a possible building block for designing a synthetic high Tc superconductor. Competition between various fascinating phases makes these materials very sensitive to external parameters and it is thus possible to dramatically tune their properties. This work on ultrathin LaNiO3 and the solid solution Nd1-xLaxNiO3 has important implications for the search for superconductivity in this class of materials.

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